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Phosphonic Acid

Phosphonic Acid

What is Phosphonic Acid?

Phosphonic acid is a breakdown product of the fungicide fosetyl-aluminium, but can also originate from direct application of phosphonate-containing fertilisers. This makes its origin tracing a complex task.

Due to the long persistence of phosphonic acid, residue levels may still be present at harvest, even if fosetyl-aluminium was applied early in the growth phase. This persistence has regulatory consequences, particularly in organic farming, where its presence can lead to problems under current EU standards. Although it is generally not considered a toxic hazard, residues can result in non-compliance and market access issues for producers and exporters.

Which food types and sectors are affected?

Residues of fosetyl-aluminium and phosphonic acid are particularly relevant in the following sectors:

  • Fruits and vegetables: Especially in grapes, lettuce, cucumbers, and citrus fruits.

  • Herbs and leafy greens: Known to accumulate residues due to high surface exposure.

  • Organic production: Phosphonic acid residues can lead to disqualification of organic certification if not authorised.

FAQ: Fosetyl-Aluminium and Phosphonic Acid in Food

What is the relationship between fosetyl-aluminium and phosphonic acid?
✔ Fosetyl-aluminium breaks down into phosphonic acid in plants as a metabolite.

Where are these residues commonly found?
✔ In fruits (especially grapes and citrus), leafy vegetables, and occasionally in organic products due to phosphonate-containing fertilisers.

Are phosphonic acid residues allowed in organic food?
✔ No, if they originate from the use of pesticides. Their presence may indicate contamination or unauthorized use.

Is fosetyl-aluminum regulated by European legislators?
No, only phosphonic acid and its salts, expressed as phosphonic acid, are regulated. Fosetyl itself is not included in the definition and is therefore not regulated by Regulation (EC) No 396/2005. However, both are analyzed together for control purposes.

What technology does GALAB use for this analysis?
✔ GALAB offers a high-sensitivity method based on the QuPPe procedure, capable of reliably detecting trace levels as low as 0.01 mg/kg – helping you stay ahead of evolving regulations. so that we can continue to check your products regarding the new regulations.

Parameters & Analytical Methods

  • State-of-the-Art Analysis

    We constantly update our spectrum of parameters to the latest developments in the food analysis sector and offer state-of-the-art analytical methods for the safety of your products.

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    We are constantly expanding our range of services in order to be able to guarantee you a comprehensive range of analyses. We offer multi-methods for mycotoxins, dioxin analysis or molecular biological analysis for GMOs and allergens. The GALAB Pesticide500Plus® multi-method can even be used for difficult matrices such as spices and herbs.

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